Resonant Raman Scattering by Charge Density and Single Particle Excitations in Semiconductor Nanostructures: A Generalized Interband-Resonant Random-Phase-Approximation Theory

Abstract

We develop a generic theory for the resonant inelastic light (Raman) scattering by a conduction band quantum plasma taking into account the presence of the filled valence band in doped semiconductor nanostructures within a generalized resonant random phase approximation (RPA). Our generalized RPA theory explicitly incorporates the two-step resonance process where an electron from the filled valence band is first excited by the incident photon into the conduction band before an electron from the conduction band falls back into the valence band emitting the scattered photon. We show that when the incident photon energy is close to a resonance energy, i.e. the valence-to-conduction band gap of the semiconductor structure, the Raman scattering spectral weight at single particle excitation energies may be substantially enhanced even for long wavelength excitations, and may become comparable to the spectral weight of collective charge density excitations (plasmon). Away from resonance, i.e. when the incident photon energy is different from the band gap energy, plasmons dominate the Raman scattering spectrum. We find no qualitative difference in the resonance effects on the Raman scattering spectra among systems of different dimensionalities (one, two and three) within RPA. This is explained by the decoherence effect of the resonant interband transition on the collective motion of conduction band electrons. Our theoretical calculations agree well (qualitatively and semi-quantitatively) with the available experimental results, in contrast to the standard nonresonant RPA theory which predicts vanishing long wavelength Raman spectral weight for single particle excitations.