Dynamic Properties of Stretched Water
P. A. Netz, F. Starr, H. Eugene Stanley, M. C. Barbosa
Abstract
We investigate the dynamics of the extended simple point charge (SPC/E) model of water in the supercooled region. The dynamics at negative pressures show a minimum in the diffusion constant D when the density is decreased at constant temperature, complementary to the known maximum of D at higher pressures. A similar trend in the rotational diffusion is also observed.
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