Disorder-induced melting of the charge order in thin films of Pr0.5Ca0.5MnO3

Abstract

We have studied the magnetic-field-induced melting of the charge order in thin films of Pr0.5Ca0.5MnO3 (PCMO) films on SrTiO3 (STO) by X-ray diffraction, magnetization and transport measurement. At small thickness (25 nm) the films are under tensile strain and the low-temperature melting fields are of the order of 20 T or more, comparable to the bulk value. With increasing film thickness the strain relaxes, which leads to a strong decrease of the melting fields. For a film of 150 nm, with in-plane and out-of-plane lattice parameters closer to the bulk value, the melting field has reduced to 4 T at 50 K, with a strong increase in the hysteretic behavior and also an increasing fraction of ferromagnetic material. Strain relaxation by growth on a template of YBa2Cu3O(7-delta) or by post-annealing yields similar results with an even stronger reduction of the melting field. Apparently, strained films behave bulk-like. Relaxation leads to increasing suppression of the CO state, presumably due to atomic scale disorder produced by the relaxation process.