Discrete breathers in polyethylene chain
A. V. Savin, L. I. Manevitch
Abstract
The existence of discrete breathers (DBs), or intrinsic localized modes (localized periodic oscillations of transzigzag) is shown. In the localization region periodic contraction-extension of valence C-C bonds occurs which is accompanied by decrease-increase of valence angles. It is shown that the breathers present in thermalized chain and their contribution dependent on temperature has been revealed.
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