Superconductivity of MI(MII0.5, Si0.5)2 (MI=Sr and Ba, MII=Al and Ga), ternary silicides with the AlB2-type structure

Abstract

Ternary silicides MI(MII0.5, Si0.5)2 (MI=Sr and Ba, MII=Al and Ga) were prepared by Ar arc melting. Powder X-ray diffraction indicates that they have the AlB2-type structure, in which Si and MII atoms are arranged in honeycomb layers and MI atoms are intercalated between them. Electrical resistivity and dc magnetization measurements revealed that Sr(Al0.5, Si0.5)2 is superconductive, with a critical temperature for superconductivity (TC) of 4.2 K, while Ba(Al0.5, Si0.5)2 is not at temperatures ranging above 2.0 K. Sr(Ga0.5, Si0.5)2 and Ba(Ga0.5, Si0.5)2 are also superconductors, with TCs of 5.1 and 3.3 K, respectively.