Magnetization steps in Zn_(1-x)Mn_xO: Four largest exchange constants and single-ion anisotropy

Abstract

Magnetization steps (MST&#39;s) from Mn pairs in several single crystals of Zn_(1-x)Mn_xO (0.0056<=x<=0.030, and in one powder (x=0.029), were observed. The largest two exchange constants, J1/kB=-18.2+/-0.5K and J1&#39;/kB=-24.3+/-0.6K, were obtained from large peaks in the differential susceptibility, dM/dH, measured in pulsed magnetic fields, H, up to 500 kOe. These two largest J&#39;s are associated with the two inequivalent classes of nearest neighbors (NN&#39;s) in the wurtzite structure. The 29% difference between J1 and J1&#39; is substantially larger than 13% in CdS:Mn, and 15% in CdSe:Mn. The pulsed-field data also indicate that, despite the direct contact between the samples and a superfluid-helium bath, substantial departures from thermal equilibrium occurred during the 7.4 ms pulse. The third- and fourth-largest J&#39;s were determined from the magnetization M at 20 mK, measured in dc magnetic fields H up to 90 kOe. Both field orientations H||c and H||[10-10] were studied. (The [10-10] direction is perpendicular to the c-axis, [0001].) By definition, neighbors which are not NN&#39;s are distant neighbors (DN&#39;s). The largest DN exchange constant (third-largest overall), has the value J/kB=-0.543+/-0.005K, and is associated with the DN at r=c. Because this is not the closest DN, this result implies that the J&#39;s do not decrease monotonically with the distance r. The second-largest DN exchange constant (fourth-largest overall), has the value J/kB=-0.080 K. It is associated with one of the two classes of neighbors that have a coordination number z=12, but the evidence is insufficient for a definite unique choice. The dependence of M on the direction of H gives D/kB=-0.039+/-0.008K, in fair agreement with -0.031 K from earlier EPR work.