Effects of Substituting Calcium for Yttrium on the Superconducting Properties of YBa2Cu3Oz Bulk Samples

Abstract

We report systematic studies of AC magnetic susceptibility and transport properties of Y(1-x)Ca(x)Ba2Cu3Oz bulk samples with 0≤ x≤ 0.4. Single phase materials, reduction of carrier concentration and decrease of Tc to 85 K were obtained at doping levels up to 20%. For Y0.7Ca0.3Ba2Cu3Oz sample the improvement of grains boundary transport and screening capabilities has been observed as a result of the optimal ratio between carrier concentration and impurity phase BaCuO2 presence. The appearence of bulk pinning and nonlinear effects starting at the highest temperature were detected also.

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