Quantum, cyclic and particle-exchange heat engines

Abstract

Differences between the thermodynamic behavior of the three-level amplifier (a quantum heat engine based on a thermally pumped laser) and the classical Carnot cycle are usually attributed to the essentially quantum or discrete nature of the former. Here we provide examples of a number of classical and semiclassical heat engines, such as thermionic, thermoelectric and photovoltaic devices, which all utilize the same thermodynamic mechanism for achieving reversibility as the three-level amplifier, namely isentropic (but non-isothermal) particle transfer between hot and cold reservoirs. This mechanism is distinct from the isothermal heat transfer required to achieve reversibility in cyclic engines such as the Carnot, Otto or Brayton cycles. We point out that some of the qualitative differences previously uncovered between the three-level amplifier and the Carnot cycle may be attributed to the fact that they are not the same 'type' of heat engine, rather than to the quantum nature of the three-level amplifier per se.