Electrical conductance of atomic contacts in liquid environments

Abstract

We present measurements of the electrical conductance $G$ at room temperature of mechanically controllable break junctions (MCBJ) fabricated from Au in different solvents (octane, DCM, DMSO, and toluene) and compare with measurements in air and vacuum. In the high conductance regime $G \agt G_0=2e^2/h$, the environment plays a minor role, as proven by the measured conductance histograms, which do not depend on the environment. In contrast, the environment significantly affects the electrical properties in the low conductance (tunneling) regime {$G << G_0$}. Here, we observe a systematic and reproducible lowering of the tunneling barrier height $ϕ$. At shorter distances, a transition to a strongly suppressed apparent barrier height is observed in octane, providing evidence for the layering of solvent molecules at small inter-electrodes separations. The presented experimental configuration offers interesting perspectives for the electrical characterization of single molecules in a controlled environment.