Temperature-Dependent X-Ray Absorption Spectroscopy of Colossal Magnetoresistive Perovskites
N. Mannella, A. Rosenhahn, M. Watanabe, B. Sell, A. Nambu, S. Ritchey, E. Arenholz, A. Young, Y. Tomioka, C. S. Fadley
Abstract
The temperature dependence of the O K-edge pre-edge structure in the x-ray absorption spectra of the perovskites La(1-x)A(x)MnO(3), (A = Ca, Sr; x = 0.3, 0.4) reveals a correlation between the disappearance of the splitting in the pre-edge region and the presence of Jahn-Teller distortions. The different magnitudes of the distortions for different compounds is proposed to explain some dissimilarity in the line shape of the spectra taken above the Curie temperature.
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