Current-induced nonequilibrium vibrations in single-molecule devices

Abstract

Finite-bias electron transport through single molecules generally induces nonequilibrium molecular vibrations (phonons). By a mapping to a Fokker-Planck equation, we obtain analytical scaling forms for the nonequilibrium phonon distribution in the limit of weak electron-phonon coupling $λ$ within a minimal model. Remarkably, the width of the phonon distribution diverges as $\simλ^{-α}$ when the coupling decreases, with voltage-dependent, non-integer exponents $α$. This implies a breakdown of perturbation theory in the electron-phonon coupling for fully developed nonequilibrium. We also discuss possible experimental implications of this result such as current-induced dissociation of molecules.