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A Definition of Metastability for Markov Processes with Detailed Balance

Francois Leyvraz, Hernan Larralde, David P. Sanders

cond-mat.stat-mecharXiv:cond-mat/0509754

Abstract

A definition of metastable states applicable to arbitrary finite state Markov processes satisfying detailed balance is discussed. In particular, we identify a crucial condition that distinguishes genuine metastable states from other types of slowly decaying modes and which leads to properties similar to those postulated in the restricted ensemble approach pen71. The intuitive physical meaning of this condition is simply that the total equilibrium probability of finding the system in the metastable state is negligible. As a concrete application of our formalism we present preliminary results on a 2D kinetic Ising model.

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