Field-induced magnetoelastic instabilities in antiferromagnetic molecular wheels

Abstract

The magnetic torque of the antiferromagnetic molecular wheel CsFe8 was studied down to 50 mK and in fields up to 28 T. Below ca. 0.5 K phase transitions were observed at the field-induced level-crossings (LCs). Intermolecular magnetic interactions are very weak excluding an explanation in terms of field-induced magnetic ordering. A magneto-elastic coupling was considered. A generic model shows that the wheel structure is unconditionally unstable at the LCs, and the predicted torque curves explain the essential features of the data well.