Anharmonicity of BaTiO3 single crystals
Y. L. Wang, A. K. Tagantsev, D. Damjanovic, N. Setter, V. K. Yarmarkin, A. I. Sokolov
Abstract
By analyzing the dielectric non-linearity with the Landau thermodynamic expansion, we find a simple and direct way to assess the importance of the eighth order term. Following this approach, it is demonstrated that the eighth order term is essential for the adequate description of the para/ferroelectric phase transition of BaTiO3. The temperature dependence of the quartic coefficient βis accordingly reconsidered and is strongly evidenced by the change of its sign above 165 C. All these findings attest to the strong polarization anharmonicity of this material, which is unexpected for classical displacive ferroelectrics.
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