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Atomic decoration for improving the efficiency of field electron emission of carbon nanotubes

Guihua Chen, Zhibing Li, Jie Peng, Chunshan He, Weiliang Wang, Shaozhi Deng, Ningsheng Xu, Chongyu Wang, Shanying Wang, Xiao Zheng, GuanHua Chen, Tao Yu

cond-mat.mtrl-sciarXiv:cond-mat/0609611

Abstract

The field electron emission from the single-walled carbon nanotubes with their open ends terminated by -BH, -NH, and -O has been simulated. The apex-vacuum barrier and the emission current have been calculated. It has been found that -BH and -NH suppress the apex-vacuum barrier significantly and lead to higher emission current in contrast to the -O terminated structure in the same applied field. The calculated binding energy implies that the carbon nanotubes terminated with -BH and -NH are more stable than those saturated by oxygen atoms or by hydrogen atoms.

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