S=1/2 antiferromagnetic Heisenberg chain with staggered fields: Copper pyrimidine and copper benzoate using the density matrix renormalization group for transfer matrices
S. Glocke, A. Klümper, H. Rakoto, J. M. Broto, A. U. B. Wolter, S. Süllow
Abstract
We consider the spin-1/2 antiferromagnetic Heisenberg chain in a staggered magnetic field describing materials such as copper benzoate and copper pyrimidine dinitrate. Using the density-matrix renormalization group for transfer matrices (TMRG) we calculate the magnetization of these materials at finite temperature and arbitrary magnetic field. These results are in excellent agreement with experimental data, allowing for a determination of the inhomogeneity parameter c of copper benzoate (c = 0.043) and copper pyrimidine dinitrate (c= 0.11). The TMRG approach can be applied to rather low temperatures yielding singular field and temperature dependences of susceptibilities.
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