Site-Selective NMR in the Quasi-1D Conductor beta-Sr0.33V2O5
Abstract
We report 51V NMR experiments in the metallic phase of the quasi-one-dimensional (1D) conductor beta-Sr0.33V2O5. The Knight shift and the quadrupole splitting of all six vanadium sites were determined as a function of the direction of magnetic field perpendicular to the conducting b-axis. Magnetic properties of the three 1D structural units are remarkably heterogeneous. In particular, the V2 ladder unit shows pronounced charge disproportionation among the two (V2a and V2b) sites. At one of these sites, the absolute value of the Knight shift and 1/(T1T) increase steeply with decreasing temperature, suggesting development of ferromagnetic correlation.
Turn this paper into a full lesson
ArcXiv compiles a staged curriculum from this paper: 8-12 lessons across beginner → advanced, synthesised section guides, visuals, flashcards, a quiz, exercises, and on-demand deep dives per section. Grounded in the abstract, never invented.