Photoisomerization in a Dissipative Environment

Abstract

We investigate photoisomerization (PI), the shape change of a molecule upon photoabsorption, in a dissipative environment using a simple spin-boson model. We identify two classes of environment depending on whether it "entangles" with the molecule. In the absence of entanglement, the environment merely causes a blue shift of the required photon frequency and reduces the quantum efficiency of PI. With entanglement the molecule can undergo a quantum phase transition between a state that photoisomerizes to a state that does not.