Photoluminescence and spectral switching of single CdSe/ZnS colloidal nanocrystals in poly(methyl methacrylate)

Abstract

Emission from single CdSe nanocrystals in PMMA was investigated. A fraction of the nanocrystals exhibiting switching between two energy states, which have similar total intensities, but distinctly different spectra were observed. We found that the spectral shift characteristic frequency increases with the pump power. By using the dynamic shift in the spectral position of emission peaks, we were able to correlate peaks from the same nanocrystal. The measured correlation is consistent with assignment of low energy lines to phonon replicas.