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A Hybrid Algebraic/Schrödinger Approach to the 2D Franck-Condon Problem

Michael W. N. Ibrahim

physics.chem-pharXiv:physics/0005036

Abstract

We use recent results regarding the geometry of the U(3) bosonic algebraic model to motivate a hybrid algebraic-Schrödinger approach to the 2D Franck-Condon problem analogous to 1D approaches. This approach allows one to analyze bent to linear Franck-Condon transitions of triatomic molecules as well as clarifies the angular momentum dependance of the Franck-Condon intensities.

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