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Optical response of small carbon clusters

K. Yabana, G. F. Bertsch

physics.chem-pharXiv:physics/9612001

Abstract

We apply the time-dependent local density approximation (TDLDA) to calculate dipole excitations in small carbon clusters. A strong low-frequency mode is found which agrees well with observation for clusters Cn with n in the range 7-15. The size dependence of the mode may be understood simply as the classical resonance of electrons in a conducting needle. For a ring geometry, the lowest collective mode occurs at about twice the frequency of the collective mode in the linear chain, and this may also be understood in simple terms.

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