Toroidal Transitions in Hydrogenic and Alkali Atoms

Abstract

In addition to electric and magnetic multipoles, the expansion of current density also yields toroidal terms, a lesser-known family of multipoles. A recent proposal, I. Kuprov $\textit{et al.}$, Science Adv. 8 abq6751 (2022), explores the possibility of a direct observation of optical toroidal transitions in hydrogen and alkali atoms in the presence of a large magnetic field that decouples the spin and the angular momentum of the electron. However, the difficulty of observing these transitions against the nearby electric dipole (E1) transitions were underestimated because of extra admixture coming from diamagnetic coupling. Here, we revisit the toroidal coupling in atoms, taking diamagnetic contribution into account, and discuss the technical challenges of observing toroidal coupling in atomic physics. We show that toroidal transition should be searched in transitions with low principal quantum numbers. The remaining strong electric-dipole contribution could be removed using an appropriate differential measurement.