Response Morphologies of a Canonical Fluctuation Diagnostic Across Ehrenfest Phase Transitions

Abstract

Microcanonical inflection-point analysis identifies MIPA-type higher-order transition structures from derivatives of the microcanonical entropy. Until recently, however, there was no canonical formulation for probing the corresponding fluctuation-level behavior directly from measurable energy fluctuations without reconstructing the density of states. Previous work addressed this limitation by introducing a canonical fluctuation diagnostic that quantifies energy-fluctuation asymmetry. Here, we investigate how this diagnostic behaves across representative first-, second-, and third-order phase transitions in the Ehrenfest classification. We consider the eight-state Potts model, the two-dimensional Ising model, and ideal three-dimensional Bose--Einstein condensation. The Potts and Ising systems exhibit a robust paired-extremum structure of the diagnostic near their respective transition regions, whereas ideal Bose--Einstein condensation exhibits a discontinuous response at the condensation temperature in the thermodynamic limit. These results show that a single fluctuation-based observable can display qualitatively distinct response morphologies across thermodynamic regimes, reflecting sensitivity to the nature of the underlying phase transition rather than serving as a direct classifier of Ehrenfest order.