Logarithmic Aging Diffusion from a Multiplicative Event Clock: Rare Event Statistics, Ultraslow Transport, and Ensemble-Time Inequivalence
Chunyan Li, Zheng Li, Yueyan Li, Haiwen Liu, X. C. Xie
Abstract
Logarithmic time dependences occur in many aging materials, but neither a t relaxation law nor a 1/t event rate uniquely identifies the underlying stochastic mechanism. We examine a specific log-aging process defined by iterating the age-conditioned forward-recurrence law after every event. This rule makes the event times multiplicative: the logarithmic ratios Un=(Tn+1/Tn) are independent and identically distributed with an explicit non-exponential density. Consequently, both the mean and the variance of the event count grow linearly with (t/t0), while the density of the nth event time has a log-normal central sector and a fixed-n algebraic far tail. These clock statistics generate logarithmic drift and spreading, an Einstein relation under local detailed balance, and ultraslow transit and target-survival laws. They also separate trajectory reproducibility from ensemble--time equivalence: the relative scatter of the time-averaged mean-square displacement decays as 1/(T/t0), although its mean does not converge to the ensemble lag MSD. We distinguish the exact event-level construction from its diffusion-limit generalized Fokker--Planck and random-clock subordination representations, and from a generalized-Langevin closure that can match selected responses and covariances but need not reproduce event counts or rare-duration statistics. The proposed clock is therefore tested not by a single logarithmic curve, but by the joint, no-refitting consistency of multiplier, count, transport, first-passage, and finite-window observables.
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