Finite relaxation protocols with minimal dissipation

Abstract

Work extraction from nonequilibrium systems is a major challenge across biological, chemical, physical, and engineering systems. Idealized protocols generally require a quasistatic relaxation stage in which the Hamiltonian is gradually adjusted through a continuum of intermediaries. Here, we consider protocols restricted to a finite number $N$ of intermediary Hamiltonians, consisting of a sequence of quench-relax steps. We determine the sequence of quenches that minimizes the dissipated work, which can be expressed in terms of a recurrence involving the Lambert function. The optimal sequence converges to the Fisher-Rao geodesic, saturating known leading-order dissipation bounds at large $N$. We obtain lower bounds on work extraction from a nonequilibrium distribution as a function of its Fisher-Rao distance to equilibrium. We extend and apply the framework in two simple models: (i) an optical trap experiment, showing that the optimal intermediary distribution can be bimodal even for unimodal initial and final distributions, and (ii) an enzyme-catalyzed reaction, showing that that accounting for relaxation time in addition to dissipation can favor barrier-lowering.