CVM studies on the atomic ordering in complex perovskite alloys
Abstract
The atomic ordering in complex perovskite alloys is investigated by the cluster variation method (CVM). For the 1/3\111\-type ordered structure, the order-disorder phase transition is the first order, and the order parameter of the 1:2 complex perovskite reaches its maximum near x=0.25. For the 1/2\111\-type ordered structure, the ordering transition is the second order. Phase diagrams for both ordered structures are obtained. The order-disorder line obeys the linear law.
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