Magnetic and Electronic Phase Diagram and Superconductivity in the Organic Superconductors k-(BEDT-TTF)2X

Abstract

The magnetic susceptibility of the organic superconductors $κ$-(h8 or d8-ET)$_{2}$$X$, $X =$ Cu(NCS)$_{2}$ and Cu[N(CN)$_{2}$]Br has been studied. A metallic phase below $T^{*} =$ 37 $\sim$ 38 K for $X =$ Cu[N(CN)$_{2}$]Br and 46 $\sim$ 50 K for $X =$ Cu(NCS)$_{2}$ has an anisotropic temperature dependence of the susceptibility and the charge transport. Partial charge-density-wave or charge fluctuation is expected to coexist with the metallic phase instead of the large antiferromagnetic fluctuation above $T^{*}$. The phase diagram and the superconductivity of $κ$-(ET)$_{2}$$X$ are discussed in connection with this phase.