Effective conductivity in association with model structure and spatial inhomogeneity of polymer/carbon black composites
Z. Garncarek, R. Piasecki, J. Borecki, A. Maj, M. Sudol
Abstract
The relationship between effective conductivity and cell structure of polyethylene/carbon composites as well as between effective conductivity and spatial distribution of carbon black are discussed. Following Yoshida's model both structures can, in a way, be said to be intermediate between the well known Maxwell-Garnett (MG) and Bruggeman (BR) limiting structures. Using TEM photographs on composites with various carbon blacks we have observed that the larger is Garncarek's inhomogeneity measure H of two-dimensional (2D) representative distribution of the carbon black, the smaller is the effective conductivity of the composite.
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