'Hole-digging' in ensembles of tunneling Molecular Magnets

Abstract

The nuclear spin-mediated quantum relaxation of ensembles of tunneling magnetic molecules causes a 'hole' to appear in the distribution of internal fields in the system. The form of this hole, and its time evolution, are studied using Monte Carlo simulations. It is shown that the line-shape of the tunneling hole in a weakly polarised sample must have a Lorentzian lineshape- the short-time half-width $ξ_o$ in all experiments done so far should be $\sim E_0$, the half-width of the nuclear spin multiplet. After a time $τ_o$, the single molecule tunneling relaxation time, the hole width begins to increase rapidly. In initially polarised samples the disintegration of resonant tunneling surfaces is found to be very fast.