Strongly Charged Polymer Brushes
Ben O'Shaughnessy, Qingbo Yang
Abstract
Charged polymer brushes are layers of surface-tethered chains. Experimental systems are frequently strongly charged. Here we calculate phase diagrams for such brushes in terms of salt concentration ns, grafting density and polymer backbone charge density. Electrostatic stiffening and counterion condensation effects arise which are absent from weakly charged brushes. In various phases chains are locally or globally fully stretched and brush height H has unique scaling forms; at higher salt concentrations we find H ~ ns(-1/3), in good agreement with experiment.
Create a lesson
Related papers
Competing routes to spontaneous flow in confined active nematics
Rahil N. Valani, Vedad Dzanic, Sumesh P. Thampi et al.
Scaling and Condensation of Dry Active Matter Around Circular Obstacles
Felipe P. S. Júnior, F. Q. Potiguar, Jorge L. C. Domingos et al.
Active Hydrodynamics Couples Polymer Organization, Shape Fluctuations, and Motility in Deformable Droplets
Ritu Raj, P. B. Sunil Kumar
Inferring interactions between active particles using harmonic traps
Arnaud Compagnie, Joscha Mecke, Ivo Buttinoni et al.
Spontaneous filament formation and network self-assembly via active phase separation
Elena Lucas, Varun Venkatesh, Amin Doostmohammadi
Sensitivity of Nucleation Thermodynamics and Kinetics to the Treatment of Long-Range Interactions
Fernanda Sulantay Vargas, Kimia Sinaeian, Amir Haji-Akbari