Universality of Ionic Criticality: Size- and Charge-Asymmetric Electrolytes

Abstract

Grand canonical simulations designed to resolve critical universality classes are reported for $z$:1 hard-core electrolyte models with diameter ratios $λ{=} a_+/a_- {\lesssim} 6$. For $z {=} 1$ Ising-type behavior prevails. Unbiased estimates of $T_c(λ)$ are within 1% of previous (biased) estimates but the critical densities are $\sim $5 % lower. Ising character is also established for the 2:1 and 3:1 equisized models, along with critical amplitudes and improved $T_c$ estimates. For $z {=} 3$, however, strong finite-size effects reduce the confidence level although classical and O$(n {\geq} 3)$ criticality are excluded.