Shear and longitudinal viscosity of non-ionic C12E8 aqueous solutions

Abstract

We present measurements of the steady shear viscosity, the longitudinal elastic modulus and the ultrasonic absorption in the one-phase isotropic liquid region of the nonionic surfactant C12E8 aqueous solutions. The overall results support the presence of two separated intervals of concentration corresponding to different structural properties. In the surfactant-rich region the temperature dependence of the steady shear viscosity follows an equation characteristic of glass-like systems. The ultrasonic absorption spectra show unambiguous evidence of viscoelastic behaviour described by a Cole-Cole relaxation formula. In the water-rich region the behaviour of the measured quantities are more complex and reflect the presence of dispersed aggregates whose size increases with temperature and concentration. An additional low frequency contribution is also observed, which is ascribed to the exchange of water molecules and/or surfactant monomers between the aggregates and the bulk solvent region.