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Entropy Production of Brownian Macromolecules with Inertia

Kyung Hyuk Kim, Hong Qian

physics.class-pharXiv:physics/0303016

Abstract

We investigate the nonequilibrium steady-state thermodynamics of single Brownian macromolecules with inertia under feedback control in isothermal ambient fluid. With the control being represented by a velocity-dependent external force, we find such open systems can have a negative entropy production rate and we develop a mesoscopic theory consistent with the second law. We propose an equilibrium condition and define a class of external forces, which includes a transverse Lorentz force, leading to equilibrium.

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