Analytic calculation of energies and wave functions of the quartic and pure quartic oscillators

Abstract

Ground state energies and wave functions of quartic and pure quartic oscillators are calculated by first casting the Schrödinger equation into a nonlinear Riccati form and then solving that nonlinear equation analytically in the first iteration of the quasilinearization method (QLM). In the QLM the nonlinear differential equation is solved by approximating the nonlinear terms by a sequence of linear expressions. The QLM is iterative but not perturbative and gives stable solutions to nonlinear problems without depending on the existence of a smallness parameter. Our explicit analytic results are then compared with exact numerical and also with WKB solutions and it is found that our ground state wave functions, using a range of small to large coupling constants, yield a precision of between 0.1 and 1 percent and are more accurate than WKB solutions by two to three orders of magnitude. In addition, our QLM wave functions are devoid of unphysical turning point singularities and thus allow one to make analytical estimates of how variation of the oscillator parameters affects physical systems that can be described by the quartic and pure quartic oscillators.