Two-photon detachment of electrons from halogen negative ions

Abstract

Absolute two-photon detachment cross sections and photoelectron angular distribution are calculated for halogen negative ions within lowest-order perturbation theory. The Dyson equation method is used to obtain the outer np ground-state wave functions with proper asymptotic behavior exp (-k r), corresponding to correct (experimental) binding energies E=k^2/2. The latter is crucial for obtaining correct absolute values of the multiphoton cross sections (Gribakin and Kuchiev 1997 Phys. Rev.A55 3760). Comparisons with previous calculations and experimental data are performed.