Piezoelectricity: A Brief History of its Discovery and Physical Principles Using the Example of Low Quartz

Abstract

Piezoelectricity is a key phenomenon in solid-state physics and has significant technological relevance. In teaching, however, it is often treated either without a historical context or an explicit link to the microscopic crystal structure, meaning that a crucial level of understanding remains untapped. This study combines the history of the discovery of piezoelectricity with its physical description within a didactically coherent framework. Building on the work of the brothers, Jacques and Pierre Curie (1880 - 1882), it demonstrated how investigations into pyroelectricity led to the identification of polarization induced by mechanical compression in hemihedral crystals such as tourmaline and quartz. The development from early qualitative experiments towards the first quantitative determination of piezoelectric constants is traced in a structured manner. Using low quartz as an example, the microscopic cause of piezoelectricity was attributed to the asymmetric displacements of silicon and oxygen ions within the orthosilicate ion tetrahedral network. This leads to the formation of macroscopic polarization owing to uncompensated dipole moments in the crystal lattice. The direct and reciprocal piezoelectric effects are qualitatively distinguished and discussed in the context of mechanical-electrical coupling. The article is aimed at students in physics and engineering as well as lecturers. It was conceived as a didactic review article (tutorial article) and serves as a structured introduction to the physical and historical foundations of piezoelectricity.